This should meet that requirement:
<xs:pattern value="(00/01)|(01/02)|(02/03)|(03/04)|(04/05)|(05/06)|(06/07)|(07/08)|(08/09)|(09/10)|(10/11)|(11/12)|(12/13)|(13/14)|(14/15)|(15/16)|(16/17)|(17/18)|(18/19)|(19/20)|(20/21)|(21/22)|(22/23)|(23/24)|(24/25)|(25/26)|(26/27)|(27/28)|(28/29)|(29/30)|(30/31)|(31/32)|(32/33)|(33/34)|(34/35)|(35/36)|(36/37)|(37/38)|(38/39)|(39/40)|(40/41)|(41/42)|(42/43)|(43/44)|(44/45)|(45/46)|(46/47)|(47/48)|(48/49)|(49/50)|(50/51)|(51/52)|(52/53)|(53/54)|(54/55)|(55/56)|(56/57)|(57/58)|(58/59)|(59/60)|(60/61)|(61/62)|(62/63)|(63/64)|(64/65)|(65/66)|(66/67)|(67/68)|(68/69)|(69/70)|(70/71)|(71/72)|(72/73)|(73/74)|(74/75)|(75/76)|(76/77)|(77/78)|(78/79)|(79/80)|(80/81)|(81/82)|(82/83)|(83/84)|(84/85)|(85/86)|(86/87)|(87/88)|(88/89)|(89/90)|(90/91)|(91/92)|(92/93)|(93/94)|(94/95)|(95/96)|(96/97)|(97/98)|(98/99)"/>
If non-capturing groups are supported I would recommend the following for efficiency:
<xs:pattern value="(?:00/01)|(?:01/02)|(?:02/03)|(?:03/04)|(?:04/05)|(?:05/06)|(?:06/07)|(?:07/08)|(?:08/09)|(?:09/10)|(?:10/11)|(?:11/12)|(?:12/13)|(?:13/14)|(?:14/15)|(?:15/16)|(?:16/17)|(?:17/18)|(?:18/19)|(?:19/20)|(?:20/21)|(?:21/22)|(?:22/23)|(?:23/24)|(?:24/25)|(?:25/26)|(?:26/27)|(?:27/28)|(?:28/29)|(?:29/30)|(?:30/31)|(?:31/32)|(?:32/33)|(?:33/34)|(?:34/35)|(?:35/36)|(?:36/37)|(?:37/38)|(?:38/39)|(?:39/40)|(?:40/41)|(?:41/42)|(?:42/43)|(?:43/44)|(?:44/45)|(?:45/46)|(?:46/47)|(?:47/48)|(?:48/49)|(?:49/50)|(?:50/51)|(?:51/52)|(?:52/53)|(?:53/54)|(?:54/55)|(?:55/56)|(?:56/57)|(?:57/58)|(?:58/59)|(?:59/60)|(?:60/61)|(?:61/62)|(?:62/63)|(?:63/64)|(?:64/65)|(?:65/66)|(?:66/67)|(?:67/68)|(?:68/69)|(?:69/70)|(?:70/71)|(?:71/72)|(?:72/73)|(?:73/74)|(?:74/75)|(?:75/76)|(?:76/77)|(?:77/78)|(?:78/79)|(?:79/80)|(?:80/81)|(?:81/82)|(?:82/83)|(?:83/84)|(?:84/85)|(?:85/86)|(?:86/87)|(?:87/88)|(?:88/89)|(?:89/90)|(?:90/91)|(?:91/92)|(?:92/93)|(?:93/94)|(?:94/95)|(?:95/96)|(?:96/97)|(?:97/98)|(?:98/99)"/>